MATERIAL SAFETY DATA SHEET

I.   PRODUCT IDENTIFICATION

Manufacturer/Supplier:

ESPI Metals

1050 Benson Way, Ashland, OR 97520

Toll Free (800) 638-2581 * Fax (541) 488-8313

E-Mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it

Product Name:     Lithium Orthophosphate, Tertiary

Formula:              Li₃PO₄

CAS Number:       10377-52-3

II.   HAZARDOUS INGREDIENTS

Hazardous Components:  Lithium Orthophosphate, Tertiary   

Percent (%):                    0-100

OSHA/PEL:                        N/E

ACGIH/TLV:                       N/E

NFPA Ratings:

Health:                              1

Flammability:                   0

Reactivity:                        0

Special:                             None

III.   PHYSICAL DATA

Boiling Point:                  N/A

Melting Point:                 1205 ^oC (2201 ^oF)

Specific Gravity:            2.5 g/cc

Solubility in H₂O:           % by wt. @ 20^oC (68 ^oF): 0.03

Appearance and Odor:   White powder, no odor.                                 

IV.   FIRE AND EXPLOSION HAZARDS DATA

Flash Point (Method used):  N/A

Autoignition Temperature:  N/A

Flammable Limits:  Upper:  N/A       Lower:  N/A

Extinguishing Media:  Dry powder, CO₂, water spray or regular foam.

Special Fire Fighting Procedures:  Wear self-contained breathing apparatus approved for firefighting and full firefighting protective clothing.  This is necessary to protect against the hazards of heat, products of combustion and oxygen deficiency.  Do not breathe smoke, gases or vapors generated.

Unusual Fire & Explosion Hazard:  N/A

Sensitivity to Mechanical Impact:  N/A            

Sensitivity to Static Discharge:  N/A

V.   HEALTH HAZARD INFORMATION

Effects of Exposure:

To the best of our knowledge the chemical, physical and toxicological properties of lithium orthophosphate tertiary have not been thoroughly investigated and recorded.  Based on data for trisodium phosphate, a similar compound, this product is expected to be extremely irritating to the eyes and minimally irritating to the skin.  It may also be irritating to the upper respiratory tract when inhaled or gastrointestinal tract when ingested.

Acute Effects:  May be extremely irritating to eyes, nose, throat and mucous membranes.

Chronic Effects:  No data available for the product.

Carcinogenicity:  NTP:  Not listed   IARC:  Not listed OSHA:  Not listed

EMERGENCY AND FIRST AID PROCEDURES:

INHALATION:  Remove to fresh air.  If breathing difficulty or discomfort occurs and persists, obtain medical attention.

INGESTION:  Rinse mouth with water.  Dilute by giving 1 or 2 glasses of water.  Do not induce vomiting.  Never give anything by mouth to an unconscious person.  See a medical doctor immediately.

SKIN:  Wash with plenty of soap and water.  Get medical attention if irritation occurs and persists.

EYE:  Flush with water for at least 15 minutes.  If irritation occurs and persists, obtain medical attention. 

Note to Physician:  Effects of oral exposure to lithium are well documented in the medical literature.  Low toxicity is anticipated.  In such cases, standard protocols for overdosage are suggested.  Treatment is otherwise symptomatic and supportive.

VI.   REACTIVITY DATA

Stability:  Stable

Conditions to Avoid:  None known

Incompatibility (Materials to Avoid):  None known

Hazardous Decomposition Products:  None known

Hazardous Polymerization:  Will not occur.

VII.   SPILL OR LEAK PROCEDURES

Steps to be Taken in Case Material is Released or Spilled:  Sweep up and place in suitable container.  Before cleanup measures begin, review the entire MSDS with particular attention to Section VIII, Special Protection Information.

Waste Disposal Method:  Dispose of in accordance with Local, State and Federal Waste Disposal Regulations.

VIII.   SPECIAL PROTECTION INFORMATION

Respiratory Protection:  When engineering controls are not adequate, wear a NIOSH/MSHA respirator approved for protection against inorganic dusts.

Ventilation:  Use local exhaust ventilation to keep airborne concentrations below exposure limits.

Gloves:  Rubber gloves.

Eyes:  Safety glasses or goggles

Clothing:  Protective gear suitable to prevent contamination.

IX.   SPECIAL PRECAUTIONS

Handling and Storage:  Avoid contact with eyes, skin or clothing.  Use with adequate ventilation.  Wear safety glasses or goggles and rubber gloves.  Wash thoroughly after handling.

Work Practices:  Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels.  Use good housekeeping and sanitation practices.  Do not use tobacco or food in work area.  Wash thoroughly before eating or smoking.  Do not blow dust off clothing or skin with compressed air.  Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.

SARA Title III, Sec. 311:  Immediate (acute) health hazard

SARA Title III, Sec. 313:  This product does not contain a toxic chemical subject to the reporting requirements of section 313 of Emergency Planning and Community Right-To-Know Act of 1986.

TSCA:  This product is not subject to TSCA 12 (b) Export Notification Requirements.  TSCA status (40 CFR 710):  Listed

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide.  ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.

Issued By:            S. Dierks

Dated:                  December 1998