MATERIAL SAFETY DATA SHEET

I.   PRODUCT IDENTIFICATION

Manufacturer/Supplier:

ESPI Metals

1050 Benson Way, Ashland, OR 97520

Toll Free (800) 638-2581 * Fax (541) 488-8313

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Product Name:     Iron Fluoride

Synonyms:           Iron (II) Fluoride, Ferrous Fluoride, Iron Difluoride

Formula:              FeF₂

CAS Number:       7789-28-8

II.   HAZARDOUS INGREDIENTS

Hazardous Component:  Iron Fluoride

Percent (%):                  0-100

OSHA/PEL:                     2.5 mg (F) /m³

ACGIH/TLV:                   2.5 mg (F) /m³

HMIS Ratings:

Health:                          2             

Flammability:               0

Reactivity:                    1

III.   PHYSICAL DATA

Boiling Point:                   N/E or N/A

Melting Point:                  ~1000 ^oC

Specific Gravity:             4.09 gm/cc at 25 ^oC

Solubility in H₂O:            Slightly soluble

Appearance and Odor:   White powder, no odor

IV.   FIRE AND EXPLOSION HAZARDS DATA

Flash Point:  N/A

Autoignition Temperature:  N/A

Flammable Limits:  Lower:  N/A      Upper:  N/A

Extinguishing Media:  Use suitable extinguishing media for surrounding materials and type of fire.

Special Fire Fighting Procedures:  Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes.  Fumes from fire are hazardous.  Isolate runoff to prevent environmental pollution.
 

Unusual Fire & Explosion Hazard:  When heated to decomposition or on contact with acid or fumes, iron fluoride may emit highly toxic fumes of fluorine.

V.   HEALTH HAZARD INFORMATION

Effects of Exposure:

To the best of our knowledge the chemical, physical and toxicological properties of iron fluoride have not been thoroughly investigated and recorded.

Iron compounds have varying toxicity.  Some iron compounds are suspected carcinogens.  In general, ferrous compounds are more toxic than ferric compounds.  Acute exposure to excessive levels of ferrous compounds can cause liver and kidney damage, altered respiratory rates and convulsions.

Fluorides may cause salivation, nausea, vomiting, diarrhea and abdominal pain, followed by weakness, tremors, shallow respiration, convulsions and coma. May cause brain and kidney damage. Chronic fluoride poisoning can cause severe bone changes, loss of weight, anorexia, anemia and dental defects

Acute Effects:

Inhalation:  May cause severe irritation to the respiratory tract and mucous membrane, acute iron poisoning, asthma attacks, excessive salivation, thirst, sweating, vomiting, colic, diarrhea and lung granulomas.  Large amounts of iron may cause iron pneumoconiosis. 

Ingestion:  May cause gastrointestinal irritation, severe nausea, vomiting, diarrhea, dehydration and thirst, muscle weakness, lethargy, cramp-like pains and central nervous system depression. 

Skin:  May cause irritation, rashes and skin granulomas.

Eyes:  May cause severe eye damage.

Chronic Effects:

Inhalation:  May cause fluorosis, pulmonary fibrosis and severe bone changes.  May cause chronic iron poisoning and pathological deposition of iron in the body tissue.

Ingestion:  May damage the liver and affect the circulatory, enzyme and nervous system.

Skin:  May cause dermatitis.

Eyes:  No data.

Target Organs:  May affect the skeleton, liver, kidneys, central nervous system, respiratory system, eyes and skin.

Medical Conditions, if any, Aggravated by Exposure:  Can cause or aggravate attacks of asthma.

Carcinogenicity:  NTP:  No    IARC:  No     OSHA:  No

EMERGENCY AND FIRST AID PROCEDURES:

INHALATION:  Remove victim to fresh air; keep warm and quiet; give oxygen if breathing is difficult and seek medical attention immediately.

INGESTION:  Give 1-2 glasses of milk or water; do not induce vomiting; seek medical attention immediately.

SKIN:  Remove contaminated clothing; brush material off skin; wash affected area with mild soap and water; seek medical attention immediately.

EYES:  Flush eyes with lukewarm water, lifting upper and lower eyelid, for at  least 15 minutes.  Seek medical attention immediately.

VI.   REACTIVITY DATA

Stability:  Stable

Conditions to Avoid:  Water/moisture, air.

Incompatibility (Material to Avoid):  Acids, oxidizing agents, air, water/moisture.

Hazardous Decomposition Products:  Hydrofluoric acid, fumes of fluorine.

Hazardous Polymerization:  Will not occur.

VII.   SPILL OR LEAK PROCEDURES

Steps to Be Taken in Case Material Is Released or Spilled:  Wear appropriate respiratory and protective equipment specified in section VIII.  Isolate spill area and provide ventilation.  Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for proper disposal.  Take care not to raise dust.

Waste Disposal Method:  Dispose of in accordance with Local, State and Federal Regulations.

VIII.   SPECIAL PROTECTION INFORMATION

Respiratory Protection:  NIOSH approved dust, mist, vapor cartridge respirator.

Ventilation:  Handle in an inert gas such as argon, in an enclosed, controlled environment.  Mechanical exhaust is not recommended.

Protective Gloves:  Rubber 

Eye Protection:  Face shield and chemical safety goggles.

Other Protective Clothing or Equipment:  Lab coat and apron, flame and chemical resistant coveralls.

IX.   SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage:  Keep container tightly closed.  Store in a cool, dry, well-ventilated area.  Wash thoroughly after use.

Other Precautions:  Handle and store under dry, protective gas such as argon.  Store away from water/moisture.  Store away from air.

Precautionary Statements:  WARNING   TOXIC   DO NOT SWALLOW OR INHALE.  Avoid contact with skin and eyes.

Work Practices:  Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels.  Use good housekeeping and sanitation practices.  Do not use tobacco or food in work area.  Wash thoroughly before eating and smoking.  Do not blow dust off clothing or skin with compressed air.  Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide.  ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.

Issued by:                  S. Dierks

Revised/Verified:        June 2011