MATERIAL SAFETY DATA SHEET

I.   PRODUCT IDENTIFICATION

Manufacturer/Supplier:

ESPI Metals

1050 Benson Way, Ashland, OR 97520

Toll Free (800) 638-2581 * Fax (541) 488-8313

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Product Name:     Copper (II) Fluoride

Formula:              CuF₂⋅2H₂O

CAS Number:       13454-88-1

II.   HAZARDOUS INGREDIENTS

Hazardous Component:  Copper Fluoride

Percent (%):                   0-100

OSHA/PEL:                       1 mg(Cu)/m³

ACGIH/TLV:                     1 mg(Cu)/m³

HMIS Ratings:

Health:                             2

Flammability:                  0

Reactivity:                       1

III.   PHYSICAL DATA

Boiling Point:                   N/A

Melting Point:                  Decomposes

Specific Gravity:             2.93 g/cc

Solubility in H₂O:             Slightly soluble in cold water

Appearance and Odor:    Blue to black powder, no odor

IV.   FIRE AND EXPLOSION HAZARDS DATA

Flash Point:  N/A

Autoignition Temperatures:  N/A

Flammable Limits in Air:  Lower:  N/A          Upper:  N/A

Extinguishing Media:  Use suitable extinguishing media for surrounding material and type of fire.

Special Firefighting Procedures:  Firefighters must wear full face, self-contained breathing apparatus with flame and chemical resistant clothing; hats, boots and gloves.  If without risk, remove material from fire area.  Cool container with water from maximum distance.

Unusual Fire and Explosion Hazards:  In case of fire may emit hydrogen fluoride.

V.   HEALTH HAZARD INFORMATION

Effects of Exposure:

To the best of our knowledge the chemical, physical an toxicological properties of copper fluoride have not been thoroughly investigated and recorded.

Copper compounds may be irritating to the skin, eyes and respiratory tract.  They may cause metal fume fever, hemolysis of the red blood cells and injury to the liver, lungs, kidneys and pancreas.  Ingestion may also cause vomiting, gastric pain, dizziness, anemia, cramps, convulsions, shock, coma and death.  Copper solutions may cause sensitization reactions.

Fluorides may cause salivation, nausea, vomiting, diarrhea and abdominal pain, followed by weakness, tremors, shallow respiration, convulsions and coma.  May cause brain and kidney damage.  Chronic fluoride poisoning can cause severe bone changes, loss of weight, anorexia, anemia and dental defects.

Acute Effects:

Inhalation:  Irritating to mucous membranes and upper respiratory tract.

Ingestion:  Harmful if swallowed, no specific details found.

Skin:  May cause irritation.

Eye:  May cause irritation.

Chronic Effects:

Inhalation:  Chronic fluorine poisoning can cause severe bone changes, loss of weight, anorexia, anemia and dental defects.

Ingestion:  Chronic fluorine poisoning can cause severe bone changes, loss of weight, anorexia, anemia and dental defects.

Skin:  None known.

Eye:  None known.

Medical Conditions, if any, Aggravated by the Chemical:  Respiratory illness.

Carcinogenicity:  NTP:  No               IARC:  No             OSHA:  No            EPA:  No

EMERGENCY AND FIRST AID PROCEDURES:

INHALATION:  Remove victim to fresh air, keep warm and quiet, give oxygen if breathing is difficult and seek medical attention.

INGESTION: Give 1-2 glasses of milk or water , do not induce vomiting, seek immediate medical attention.  Never induce vomiting or give anything by mouth to an unconscious person. 

SKIN:  Remove contaminated clothing, brush material off skin, wash affected area with mild soap and water.  Seek medical attention if symptoms persist.

EYES:  Flush with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes.  Seek medical attention if symptoms persist.

VI.   REACTIVITY DATA

Stability:  Stable

Conditions to Avoid:  Water/moisture

Incompatibility (Material to Avoid):  Strong acids.

Hazardous Decomposition Products:  Metal oxide fume, contact with acids may produce HF which is a highly toxic and corrosive material.

Hazardous Polymerization:  Will not occur.

VII.   SPILL OR LEAK PROCEDURES

Steps to Be Taken in Case Material is Released or Spilled:  Wear appropriate respiratory and protective equipment specified in section VIII.  Isolate spill area and provide ventilation.  Cover spill with dry sand or vermiculite.  Mix well and carefully transfer to a container.

Waste Disposal Method:  In accordance with State, Federal and Local regulations.

VIII.   SPECIAL PROTECTION INFORMATION

Respiratory Protection:  NIOSH approved respirator.

Ventilation: Handle in a controlled, enclosed environment in an inert gas such as argon.  Use local exhaust to maintain low levels of exposure.  General exhaust is not recommended.

Protective Gloves:  Rubber

Eye Protection:  Safety goggles.

Other Protective Clothing or Equipment:  Protective gear suitable to prevent contamination.

IX.   SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage:  Keep container tightly closed.  Store in a cool, dry, well-ventilated area.  Wash thoroughly after use.  Store away from water/moisture.

Work Practices:  Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels.  Use good housekeeping and sanitation practices.  Do not use tobacco or food in work area.  Wash thoroughly before eating and smoking.  Do not blow dust off clothing or skin with compressed air.  Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.

TSCA Registered:  Yes

DOT Regulations:

Hazard Class:                    6.1

Identification Number:     UN3288

Packing Group:                 III

Proper Shipping Name:    Toxic solid, inorganic, n.o.s., (copper fluoride)

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide.  ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.

Issued by:             S. Dierks

Dated:                  January 2005